Kinetic control: A reaction in which the product ratio is determined by the rate at which the products are formed. Thermodynamic product: The more stable product formed in a chemical reaction. Thermodynamic control: A reaction in which the product ratio is determined by the relative stability of the products.
Characteristics · In general, short reaction times favour kinetic control, whereas longer reaction times favour thermodynamic reaction control. · If a reaction ... Scope · In enolate chemistry · Characteristics |
| Кинетический контроль |  |
О кинетическом контроле прохождения химической реакции говорят, когда из двух или более возможных продуктов реакции образуется преимущественно продукт более быстрой реакции, как правило, менее энергетически выгодный. Википедия
Stereoelectronics of products vs. transition states. – Thermodynamic control: Ley spiroacetal formation. – Kinetic control: 1,2-diaxial processes. • Steric/ ... |
Videolar 20 сент. 2023 г. · The product of an irreversible reaction depends only on relative rates, not on stability. Such reactions are said to be under kinetic control. |
16 мар. 2021 г. · I know thermodynamic occurs at higher temperature and forms a more stable product, I know kinetic forms faster. |
9 июн. 2019 г. · A new definition for this switching point is proposed: the time at which the rates of formation of the competing products are equal. |
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