8 мая 2019 г. · This charge stabilization of the developing negative in the TS and the full negative in the intermediate is often called electrostatic catalysis ...

27 янв. 2020 г. · Electrostatic catalysis enhances reaction rates through the arrangement of charged groups within the enzyme's active site to stabilize ...

26 янв. 2024 г. · The reaction is effectively catalysed over a molecularly functionalized electrode surface exploiting voltage-controlled electric fields confined ...

is gene manipulation, which makes possible to study the contribution of a given charged or polar side chain to the overall effect (e.g. reaction rates or.

Metal ion catalysis is essentially a type of electrostatic catalysis, where the interactions form between the metal ion cofactors and the substrates. This can ...

Electrostatic catalysis has been well known since Pocker and co-workers observed rate enhancements for heterolysis reactions using an external electric field ( ...

2 мар. 2016 г. · It is often thought that the ability to control reaction rates with an applied electrical potential gradient is unique to redox systems.

(Bottom middle) The general model for electrostatic catalysis whereby an electric field can only have a beneficiary effect on catalysis through preferential ...

To provide a positive charge able to interact with the partial negative charge on the substrate's ether oxygen, the ammonium group of Lys-88 must reach into the ...